Chemistry 3000
Quantitative Analysis
Fall 2006

• Course Name: Quantitative Analysis
• Time/Location: Monday, Wednesday, and Friday 12:30-1:20, BUS-319
• Instructor: Stephen Bialkowski
• Instructors Office: ML 359
• Instructors Phone: 797-1907
• Instructors email: Stephen.Bialkowski@usu.edu
• Student Office Hours: Monday 2:30-3:30 p.m., Wednesday 1:30-2:30 p.m. I will be in and out of the Chemistry 3005 laboratories and it is easy to catch me there. Other arrangements may be made. Experience has shown that E-mail questions works very well.

General Information

Required Text: Daniel C. Harris Quantitative Chemical Analysis 7th Edition, W. H. Freeman and Company, New York 2006

Course Content: This is a lecture course addressing aspects of modern chemical analysis with an emphasis on chemical equilibrium. Volumetric, gravimetric, and instrumental methods are described.

Learning Objectives:

• Comprehend the importance of stoichiometry, chemical equilibrium and kinetics in analysis.
  
• Formulate concepts of validation of data and experimental design
  
• Comprehend concept of and perform chemical measurement calibration
  
• Apply and assess concepts of availability and evaluation of analytical standards and formulate standardization methodology
  
• Demonstrate knowledge of sampling methods for all states of matter
  
• Use statistical methods for evaluating and interpreting data
  
• Assess sources of error in chemical and instrumental analysis and account for errors in data analysis
  
• Recognize interferences in chemical and instrumental analysis
  
• Apply theory and operational principles of analytical instruments
  
• Distinguish between qualitative and quantitative measurements and compare and critically select methods for elemental and molecular analyses
  
• Professional Ethics

Lectures: Lectures cover basic statistics, chemical equilibrium, gravimetric analysis, volumetric analysis, acid-base chemistry, complexation, spectrophotometry, and separations.

Homework: Students should work through all Exercises at the end of each Chapter. Certain Problems will be assigned. These Problems should be worked for your own benefit. It is not necessary to work all Problems if you have a good grasp of the concepts and computation skills. This homework will not be graded but the successful student should work them through and check the results.

Examinations: There will be two in class examinations, each worth 100 points, and a final examination worth 150 points. The examinations will be based on homework (Exercises and assigned Problems) and/or concepts addressed in the lectures. The test questions may be taken from the homework verbatim, or may be altered to have different numerical values or reagents. Questions can be synthesized from several homework problems.

Grading: Grades will be based on your performance on the three examinations. Point scores will be added and a percent score calculated. The guaranteed grade cut-off of 90+% A, 80%-89% B, 70%-79% C, 55%-69% D will be used. +/- scores will be used as prescribed in the Catalog. The percentile scores may be adjusted, only upward, to curve the percent scores if the examinations appear to be too difficult and if the class, as a whole, did not perform well on specific questions. Past experience has shown that those students who do the homework and understand what they have done pass with high scores.

Withdrawal Policy: This course will follow the University policy on withdrawals stated in the current Undergraduate Catalog. Drop dates are listed in the Schedule of Classes.

Missed Examination Policy: Students may be excused from an examination in cases of emergency. Documentation must be supplied to be excused. In cases of excused absence, grades will be assigned based on % of adjusted total score. No repetition of examinations is permitted.

Attendance Policy: Attendance will not be taken. Attendance is mandatory for successful performance in this course.

Student Disability Statement: Any student with a disability that requires accommodations must contact the Instructor. The disability must be documented by the Disability Resource Center. Course materials may be requested in alternative formats.

Assessment: An American Chemical Society standardized final will be used for course assessment and performance evaluation purposes.

Back Up To Lists

Lectures

Tentative Lecture Schedule

Dates	Subject	Reading	Additional Homework*
8/28-8/30	Analytical Process	Ch. 0 & 1	1-12, 13, 14, 19, 31
9/1-9/6	Experimental Error	Ch. 3	3-10, 12, 13, 16
9/8-9/11	Statistics	Ch. 4	4-1, 8, 11, 13, 20, 22
9/13-9/18	Quality Assurance/Calibration	Ch. 5	5-2, 11, 15, 18, 22, 29
9/20-9/22	Chemical Equilibrium	Ch. 6	6-4, 6, 8, 14, 19, 25, 36, 41, 48
9/25-9/27	Watch for Announcement		Stephen Bialkowski out on business
9/29	Gravimetric Analysis	Ch. 27	27-10, 12, 21
10/2-10/6	Volumetric Analysis	Ch. 7	7-7, 16, 28
10/4	First Examination
10/9-10/11	Activity-Systematic Equilibria	Ch. 8	8-3, 4, 12, 15, 19, 20
10/13	Monoprotic Acid-Base	Ch. 9	9-2, 3, 11, 20, 32, 36
10/16	Polyprotic Acid-Base	Ch. 10	10-4, 11, 17, 22, 23, 26, 30
10/18	Acid-Base Titrations	Ch. 11	11-2, 6, 15, 17, 19, 31, 45
10/20	Fall Break
10/23	EDTA Titrations	Ch. 12	12-2, 3, 6, 30, 34
10/25	Electrochemistry	Ch. 14	14-1, 5, 10, 17, 26
10/27-10/30	Potentiometry	Ch. 15	15-1, 4, 9, 21, 26, 29, 34
11/1	Second Examination
11/3-11/6	Spectrophotometry	Ch. 18	18-5, 10, 13, 18, 23
11/8-11/10	Applied Spectrophotometry	Ch. 19	19-4, 8, 12
11/13	Atomic Spectroscopy	Ch. 21	21-1, 19, 21
11/15-11/20	Analytical Separations	Ch. 23	23-7, 11, 15, 17, 27, 44
11/22-11/26	Turkey Break
11/27-11/29	Gas Chromatography	Ch. 24	24-9, 18, 25
12/1-12/4	Liquid Chromatography	Ch. 25	25-4, 12, 17, 21, 29
12/6-12/8	Chromatographic Methods	Ch. 26	26-4, 7, 11, 20, 30, 33
12/13	Final Examination Wednesday 11:30-1:20

* The homework problems are in addition to the Exercises that all students should work through. Exercises have worked-out solutions at the end of the book while the Problems may only give the answers.

Back Up To List

Notes

• Note on mathematics: Algebra is used in this course. A successful student will be proficient at manipulating equations by the middle of the quarter. Think of algebra as fun!?. There is great satisfaction in obtaining a symbolic result for a complex system.
• A note regarding Chemistry 3005 laboratory: Quantitative Analysis Laboratory is graded separate from lecture. Laboratory performance does not influence lecture grade, or visa versa. Laboratory manuals will be available in the Taggert Student Union copy center. You need to have a manual before coming to the first class since it contains the check in list and the safety agreement. A bound laboratory notebook is required. Students taking the laboratory should read Chapter 2 and Chapter 28 in the text. Pay attention to the use of analytical balances, burettes, volumetric glassware, and sample drying.

Back Up to List

Links

Here are some lecture overheads and other materials I have put "on-line"

• Steps in an Analysis
• Determinant Errors
• Propagation of Errors
• Statistics for Analysis
• Statistical Treatment Narrative
• The Normal Distribution
• Student's t
• Testing for significance with Student's t
• F-Test
• Q-Test
• Statistical Treatment of Data Illustration
• Linear Regression
• Sample and Sampling Variance
• Excel Calibration Example
• Dr. Brown QA-QC Overheads
• Introduction to Chemical Equilibria
• Gravimetric Analysis
• Titrimetric Analysis
• Silver Halide Excel Spreadsheet
• Polyprotic Acids and Conjugate Bases
• First Examination and Key from 1998
• First Examination and Key from 1999
• First Examination and Key from 2002
• Activity Calculation Example
• Introduction to Systematic Equilibrium Calculations
• Distribution of Equilibrium Species including
  1. Distributions of Poly-Protic Acid Species
  2. Use of Distributions in pH Problems
  3. Use of Distributions in Solubility Problems
  4. Distribution Of Complexed Metal Ion Species
• Systematic Approach to Strong Acid/Strong Base Titration
• Systematic Approach to Weak Acid/Strong Base Titrations
• Examples of Mixed (2) Acid Cases
• Equations Governing Polyprotic Acid Titrations (tough stuff)
• Triprotic Acid Titration Curve Predictions
• Carbonate Solubility
• Second Examination and Key from 1999
• Second Examination and Key from 1998
• Second Examination and Key from 2002
• Basic Electrochemistry Concepts/Calculations
• pH and other ion-selective electrodes
• Note of caution: This year's final will be different than those listed below. It will be a standardized examination for quantitative chemical analysis in multiple-choice format.
  • Final Examination and Key from 1998
  • Final Examination and Key from 1999
  • Final Examination and Key from 2002

Back Up To Lists

Global Links

• Dr. Tom Spudich's Analytical Chemistry Springboard site.
• Dr James K. Hardy's pages at the University of Akron
• Dr Brian Lamp's "Quantitative Analysis" at Truman State University
• Umeå University is a resource for analytical chemistry information
• Institute of Analytical Chemistry in Vienna
• Journal of Chemical Education summaries
• IUPAC (International Union of Pure and Applied Chemistry) compendium of Analytical Nomenclature the definitive collection of terms used in chemical analysis. 
• NIST SI units
• NIST Guide to expressing uncertainty
• NIST SRM Web Site Home

This page was last edited Friday, September 29, 2006