Utah State University:
48. K. Rudzka, A. M. Arif, T. Borowski, and L. M. Berreau, "A Trinuclear Ni(II) Enediolate Complex: Synthesis, Characterization, and O2 Reactivity," Submitted for publication.
47. G. K. Ingle, R. W. Watkins, A. M. Arif, and Lisa M. Berreau, "Divalent Metal Complexes of an Amide-appended N3O-donor Ligand: Synthesis, Structural and Spectroscopic Features, and Amide Methanolysis Reactivity," J. Coord. Chem. 2008, 61, 61-67.
46. G. K. Ingle, M. M. Makowska-Grzyska, A. M. Arif, and L. M. Berreau, "Divalent Nickel, Cobalt, and Iron Complexes of an Amide-appended N2S2 Ligand: Synthesis, Characterization and Reactivity with Hydroxide Anion," Eur. J. Inorg. Chem. 2007, 5262-5269.
45. L. M. Berreau, "Coordination and Bioinorganic Chemistry of Aryl-Appended Tris(2-pyridylmethyl)amine Ligands," Comments on Inorg. Chem. 2007, 28, 123-171.(Internet page)
44. E. Szajna-Fuller, G. K. Ingle, R. W. Watkins, A. M. Arif, and L. M. Berreau, "Amide Hydrolysis Reactivity of a N4O-ligated Zinc Complex: Comparison of Kinetic and Thermodynamic Parameters with those of the Corresponding Amide Methanolysis Reaction," Inorg. Chem. 2007, 46, 2353-2355. (PDF)
43. G. K. Ingle, M. M. Makowska-Grzyska, E. Szajna-Fuller, I. Sen, J. C. Price, A. M. Arif, and L. M. Berreau, "Influence of Chelate Ligand Structure on the Amide Methanolysis Reactivity of Mononuclear Zinc Complexes," Inorg. Chem. 2007, 46, 1471-1480. (PDF)
42. R. A. Allred, S. A. Huefner, K. Rudzka, A. M. Arif, and L. M. Berreau, "A Cadmium Hydroxide Complex of a N3S-donor Ligand Containing Two Hydrogen Bond Donors: Synthesis, Characterization, and CO2 Reactivity," Dalton Transactions 2007, 351-357. (HTML)
41. E. Szajna-Fuller, B. M. Chambers, A. M. Arif, and Lisa M. Berreau, "Carboxylate Coordination Chemistry of a Mononuclear Ni(II) Center in a Hydrophobic or Hydrogen Bond Donor Secondary Environment: Relvance to Acireductone Dioxygenase," Inorg. Chem. 2007, 46, 5486-5498. (PDF)
40. E. Szajna-Fuller, K. Rudzka, A. M. Arif, and L. M. Berreau, "Acireductone Dioxygenase (ARD)-type Reactivity of a Ni(II) Complex having Monoanionic Coordination of a Model Substrate: Product Identification and Comparisons to Unreactive Analogs," Inorg. Chem. 2007, 46, 5499-5507. (PDF)
39. K. Rudzka, A. M. Arif, and L. M. Berreau, "Glyoxalase I-type Hemithioacetal Isomerization Reactivity of a Mononuclear Ni(II) Deprotonated Amide Complex," J. Am. Chem. Soc. 2006, 128, 17018-17023.(HTML/PDF)
38. R. A. Allred, K. Doyle, A. M. Arif, and L. M. Berreau, "Solvent Effects on the Structural and Formyl Substrate Reactivity Properties of a Nitrogen/Sulfur-ligated Zinc Hydroxide Complex," Inorg. Chem. 2006, 45, 4097-4108. (HTML/PDF)
37. L. M. Berreau,"Kinetic and Mechanistic Studies of the Reactivity of Zn-OHn (n = 1 or 2) Species in Small Molecule Analogs of Zinc-containing Metalloenzymes," Advances in Physical Organic Chemistry 2006, 41, 79-181.
36. L. M. Berreau, "Bioinorganic Chemistry of Group 12 Complexes Supported by Tetradentate Tripodal Ligands having Internal Hydrogen Bond Donors," Eur. J. Inorg. Chem. 2006, 273-283. (PDF)
35. L. M. Berreau, A. Saha, A. M. Arif, "Thioester Hydrolysis Reactivity of Binuclear Zinc Hydroxide Complexes: Investigating Reactivity Relevant to Glyoxalase II Enzymes," Dalton Trans. 2006, 183-192. (HTML/PDF)
34. E. Szajna, A. M. Arif, and L. M. Berreau, "Aliphatic Carbon-Carbon Bond Cleavage Reactivity of a Mononuclear Ni(II) Cis-B-Keto-Enolate Complex in the Presence of Base and O2: A Model Reaction for Acireductone Dioxygenase (ARD)," J. Am. Chem. Soc. 2005, 127, 17186-17187.(HTML/PDF)
33. A. L. Fuller, R. W. Watkins, A. M. Arif, and L. M. Berreau, "Synthesis and Characterization of a Series of N3O-ligated Mononuclear Mn(II) Halide Complexes,"Inorg. Chim. Acta 2006, 359, 1282-1290.
32. K. Rudzka, A. M. Arif, and L. M. Berreau, "Chemistry of a Ni(II) Acetohydroxamic Acid Complex: Formation, Reactivity with Water, and Attempted Preparation of Zinc and Cobalt Analogs," Inorg. Chem. 2005, 44, 7234-7242. (PDF)
31. E. Szajna, M. M. Makowska-Grzyska, C. C. Wasden, A. M. Arif, and L. M. Berreau, "A Deprotonated Intermediate in the Amide Methanolysis Reaction of a N4O-ligated Mononuclear Zinc Complex," Inorg. Chem. 2005, 44, 7595-7605. (PDF)
30. A. L. Fuller, R. W. Watkins, K. R. Dunbar, A. V. Prosvirin, A. M. Arif, and L. M. Berreau, "Manganese(II) Chemistry of a New N3O-donor Chelate Ligand: Synthesis, X-ray Structures, and Magnetic Properties of Solvent- and Oxalate-bound Complexes," Dalton Transactions 2005, 1891-1896. (HTML)
29. M. M. Makowska-Grzyska, K. Doyle, R. A. Allred, A. M. Arif, D. C. Bebout, and L. M. Berreau, "Structural, Spectroscopic, and Reactivity Properties of N2S2(thioether)O(amide)-Ligated Hg(II) Complexes: The First Examples of Hg(II)-Mediated Amide Cleavage," Eur. J. Inorg. Chem. 2005, 822-827. (PDF)
28. K. Rudzka, M. M. Makowska-Grzyska, E. Szajna, A. M. Arif, and L. M. Berreau, "Neutral Acetohydroxamic Acid Coordination to a Mononuclear Ni(II) Center Stabilized by a Intramolecular Hydrogen-bonding Interaction," Chem. Commun. 2005, 489-491. (HTML)
27. K. J. Tubbs, E. Szajna, B. Bennett, J. A. Halfen, R. W. Watkins, A. M. Arif, L. M. Berreau, "Mononuclear Nitrogen/sulfur-Ligated Cobalt(II) Methoxide Complexes: Structural, EPR, Paramagnetic 1H NMR, and Electrochemical Investigations," Dalton Transactions 2004, 2398-2399. (HTML)
26. E. Szajna, P. Dobrowolski, A. L. Fuller, A. M. Arif, and L. M. Berreau, "NMR Studies of Mononuclear Octahedral Ni(II) Complexes of Tris((2-pyridyl)methyl)amine-type Ligands," Inorg. Chem. 2004, 43, 3988-3997. (PDF)
25. T. Chandra, R. A. Allred, B. J. Kraft, L. M. Berreau, and J. M. Zaleski, "Syntheses and Thermal Reactivities of Tetradententate Metalloenediynes of Cu(II) and Zn(II)," Inorg. Chem. 2004, 43, 411-420. (PDF) (Cover article)
24. M. M. Makowska-Grzyska, E. Szajna, C. Shipley, A. M. Arif, M. H. Mitchell, J. A. Halfen, L. M. Berreau, "First Row Divalent Transition Metal Complexes of Aryl-Appended Tris((pyridyl)methyl)amine Ligands: Syntheses, Structures, Electrochemistry, and Hydroxamate Binding Properties," Inorg. Chem. 2003, 42, 7472-7488. (PDF)
23. K. J. Tubbs, A. L. Fuller, B. Bennett, A. M. Arif, L. M. Berreau, "Mononuclear N3S(thioether)-Ligated Copper(II) Methoxide Complexes: Synthesis, Characterization, and Hydrolytic Reactivity," Inorg. Chem. 2003, 42, 4790-4791. (PDF)
22. K. J. Tubbs, A. L. Fuller, B. Bennett, A. M. Arif, M. M. Makowska-Grzyska, L. M. Berreau, "Evaluation of the Influence of a Thioether Substituent on the Solid State and Solution Properties of N3S-ligated Copper(II) Complexes," Dalton Transactions 2003, 3111-3116. (PDF)
21. L. M. Berreau, "Nitrogen/Sulfur Ligands Possessing Internal Hydrogen Bond Donors: A Synthetic Strategy for Modeling Secondary Interactions at Biological Zinc Centers," (Invited Mini-review) ChemTracts-Inorganic Chemistry 2003, 16, 23-36.
20. R. A. Allred, Lenore H. McAlexander, Atta M. Arif, and Lisa M. Berreau, "Chemistry of a Binuclear Cadmium(II) Hydroxide Complex: Formation from H2O, CO2 Reactivity, and Comparison to a Zinc Analog," Inorg. Chem. 2002, 41, 6790-6801. (PDF)
19. D. K. Garner, S. B. Fitch, L. H. McAlexander, L. M. Bezold, A. M. Arif, L. M. Berreau, "Mononuclear Nitrogen/Sulfur-ligatd Zinc Methoxide and Hydroxide Complexes: Investigating Ligand Effects on the Hydrolytic Stability of Zinc Alkoxide Species," J. Am. Chem. Soc. 2002, 124, 9970-9971. (PDF)
18. M. M. Makowska-Grzyska, P. C. Jeppson, R. A. Allred, A. M. Arif, L. M. Berreau, "Modeling Substrate- and Inhibitor-bound Forms of Liver Alcohol Dehydrogenase: Chemistry of Mononuclear Nitrogen/Sulfur-ligated Zinc Alcohol, Formamide, and Sulfoxide Complexes," Inorg. Chem. 2002, 41, 4872-4887.(PDF)
17. D. K. Garner, R. A. Allred, K. J. Tubbs, A. M. Arif, L. M. Berreau, "Synthesis and Characterization of Mononuclear Zinc Aryloxide Complexes Supported by Nitrogen/Sulfur Ligands Possessing an Internal Hydrogen Bond Donor," Inorg. Chem. 2002, 41, 3533-3541. (PDF)
16. R. A. Allred, A. M. Arif, L. M. Berreau, "A Binuclear Cadmium(II) Hydroxide Complex and its CO2 Reaction Product," Dalton Transactions 2002, 300-301.(PDF)
15. L. M. Berreau, M. M. Makowska-Grzyska, A. M. Arif, "Modeling the Active Site Chemistry of Liver Alcohol Dehydrogenase: Mononuclear Zinc Methanol and N,N-Dimethylformamide Complexes of a Nitrogen/Sulfur Ligand Possessing an Internal Hydrogen Bond Donor," Inorg. Chem. 2001, 40, 2212-2213.(PDF)
14. L. M. Berreau, M. M. Makowska-Grzyska, A. M. Arif, "Amide Alcoholysis in Mononuclear Zinc and Cadmium Complexes Ligated by Thioether Sulfur and Nitrogen Donors," Inorg. Chem. 2000, 4390-4391.(PDF).
13. L. M. Berreau, R. A. Allred, M. M. Makowska-Grzyska, A. M. Arif, "Synthesis and Structure of a Nitrogen/Sulfur-ligated Zinc Hydroxide Complex," Chem. Commun. 2000, 1423-1424.(PDF)
Graduate and Postdoctoral Career:
12. L. M. Berreau, J. A. Halfen, V. G. Young, Jr., W. B. Tolman, "Heterocyclic Donor Influences on the Binding and Activation of CO, NO, and O2 by Copper Complexes of Hybrid Triazacyclononane-pyridyl Ligands," Inorg. Chim. Acta, 2000, 297, 115-128. (Thematic issue honoring Professor Stephen J. Lippard)
11. L.M. Berreau, S. Mahapatra, J. A. Halfen, R. P. Houser, V. G. Young, Jr., W. B. Tolman, "Modeling Catecholase Activity: Reactivity of Peroxo- and Bis(µ-oxo)dicopper Complexes with Catechols," Angew. Chem., 1999, 38, 207-210.
10. L. M. Berreau, J. A. Halfen, V. G. Young, Jr., W. B. Tolman, "Synthesis and Copper Coordination Chemistry of Hindered 1,4,7-Triazacyclononane Ligands with Amide Appendages," Inorg. Chem., 1998 , 37, 1091-1098.(PDF)
9. S. Itoh. H. Nakao, L. M. Berreau, T. Kondo, M. Komatsu, S. Fukuzumi, "Mechanistic Studies of Aliphatic Ligand Hydroxylation of a Copper Complex by Dioxygen: A Model Reaction for Copper Monooxygenases," J. Am. Chem. Soc., 1998 , 120, 2890-2899.(PDF)
8. J. A. Halfen, B. A. Jazdzweski, S. Mahapatra, L. M. Berreau, E. C. Wilkinson, L. Que, Jr., W. B. Tolman, "Synthetic Models of the Inactive Copper(II)-Tyrosinate and Active Copper(II)-Tyrosyl Radical Forms of Galactose and Glyoxal Oxidases," J. Am. Chem. Soc., 1997 , 119, 8217-8227.(PDF)
7. S. D. Gray, J. L. Thorman, L. M. Berreau, L. K. Woo, "Alkoxide, Amido, And Imido Derivatives of Titanium(IV) Tetratolylporphyrins," Inorg. Chem., 1997 , 36, 278-283.(PDF)
6. L. M. Berreau, S. Mahapatra, J. A. Halfen, V. G. Young, Jr., W. B. Tolman, "Independent Synthesis and Structural Characterization of a Mononuclear Copper Hydroxide Complex Previously Assigned as a Copper-Superoxide Species," Inorg. Chem., 1996 , 35, 6339-6342.(PDF)
5. L. M. Berreau, V. G. Young, Jr., L. K. Woo, "Synthesis, Characterization, and Reactivity of Sulfido and Selenido Molybdenum(IV) Porphyrin Complexes. X-ray Structure of Sulfide(tetratolylporphyrinato)molybdenum(IV)," Inorg. Chem., 1995 , 34, 3485-3490.
4. L. M. Berreau, L. K. Woo, "Sulfur and Selenium Atom Transfer Reactions of Tin Porphyrins," J. Am. Chem. Soc., 1995 , 117, 1314-1317.
3. L. M. Berreau, V. G. Young, Jr., L. K. Woo, "Synthesis, Characterization and Reactivity of Imido Titanium(IV) Porphyrin Complexes. X-ray Structure of Phenylimido(tetratolylporphyrinato)titanium(IV)," Inorg. Chem., 1995 , 34, 527-529.
2. L. M. Berreau, J. A. Hays, V. G. Young, Jr., L. K. Woo, "Synthesis of Early Transition Metal Porphyrin Halide Complexes. First Structural Characterization of a Vanadium(III) Porphyrin Complex," Inorg. Chem., 1994 , 33, 105-108.
1. L. K. Woo, J. G. Goll, L. M. Berreau, R. Weaving, "Oxygen Atom Transfer Reactions of Chromium Porphyrins: An Electronic Rationale for Oxo Transfer versus mu-oxo Product Formation," J. Am. Chem. Soc., 1992 , 114, 7411-7415.
Utah State University:
4. Russell A. Allred, Atta M. Arif, and Lisa M. Berreau, "Modeling Sulfur Ligation at Hydrolytic Metal Centers: Synthesis, Structural Characterization, and Hydrolytic Activity of An N/S-Ligated Zinc Hydroxide Complex," Poster presentation at the 219th ACS National Meeting, San Francisco, CA, March 2000.
3. Magdalena M. Makowska-Grzyska, Atta M. Arif, and Lisa M. Berreau, "Modeling the Reactivity of Sulfur-ligated Zinc Amidases: Amide Alcoholysis in New Mononuclear Zinc Complexes Ligated by Thioether and Nitrogen Donors," Poster presentation at the 219th ACS National Meeting, San Francisco, CA, March 2000.
2. L. M. Berreau, R. A. Allred, M. M. Makowska-Grzyska, A. M. Arif, "Structural, Spectroscopic, and Formamide Cleavage Properties of a New Family of N/S-ligated Zn2+ and Cd2+ Complexes: Relevance to Zn2+-Containing Peptide Deformylase," Poster presentation at the Metals in Biology Gordon Conference, Ventura, CA, Jan. 2000.
1. L. M. Berreau, M. M. Makowska-Grzyska, R. A. Allred, J. L. Hubbard, A. M. Arif, M. Pink, "Amide-appended Nitrogen/Sulfur Ligands for Modeling the Active Site of Peptide Deformylase," Poster presentation at The 9th International Conference on Bioinorganic Chemistry, Minneapolis, MN, July, 1999.
Graduate and Postdoctoral Career:
4. L. M. Berreau, J. A. Halfen, S. Mahaptra, V. G. Young, Jr., W. B. Tolman, "Copper-Dioxygen Chemistry with Amide-appended Ligands," Poster presentation at the Metals in Biology Gordon Conference, Ventura, CA, Jan. 1997.
3. L. M. Berreau, J. A. Halfen, V. G. Young, Jr., W. B. Tolman, "Modeling Copper Monooxygenase Activity in Proteins: Ligand Oxygenation Mediated by Discrete Dicopper/O2 Complexes," Poster presentation at the Conference on Oxygen Intermediates in Nonheme Metallobiochemistry, Minneapolis, MN, June 1996.
2. L. M. Berreau, J. A. Hays, V. G. Young, Jr., L. K. Woo, "Synthesis, Characterization, and Reactivity of Sulfido and Selenido Molybdenum(IV) Porphyrin Complexes. X-ray Structure of Sulfido(tetratolylporphyrinato)molybdenum(IV)," Oral presentation at the 207th ACS National Meeting, San Diego, CA, March, 1994.
1. L. M. Berreau, J. A. Hays, V. G. Young, Jr., L. K. Woo, "Synthesis of Early Transition Metal Porphyrin Complexes: First Structural Characterization of a Vanadium(III) Porphyrin Complex," Poster presentation at the 206th ACS National Meeting, Chicago, IL, August, 1993.